| Year | Tournament | Result | Player | Age | Nation |
|---|---|---|---|---|---|
| 2006 | Wimbledon | R64 | Tatiana Golovin | 18 | France |
| 2006 | Wimbledon | R128 | Gaël Monfils | 19 | France |
| 2006 | Wimbledon | R128 | Florent Serra | 25 | France |
| 2006 | Wimbledon | R128 | Jean-Christophe Faurel | 25 | France |
| 2006 | Wimbledon | R128 | Richard Gasquet | 20 | France |
| 2006 | Wimbledon | R128 | Paul-Henri Mathieu | 24 | France |
| 2006 | Wimbledon | R128 | Gilles Simon | 21 | France |
| 2006 | Wimbledon | R128 | Virginie Razzano | 23 | France |
| 2006 | Wimbledon | R128 | Camille Pin | 24 | France |
| 2006 | Wimbledon | R128 | Stéphanie Foretz | 25 | France |
| 2006 | Wimbledon | R128 | Nathalie Dechy | 27 | France |
| 2006 | Wimbledon | R128 | Émilie Loit | 27 | France |
| 2006 | French Open | Q | Julien Benneteau | 24 | France |
| 2006 | French Open | R16 | Gaël Monfils | 19 | France |
| 2006 | French Open | R16 | Amélie Mauresmo | 26 | France |
| 2006 | French Open | R32 | Paul-Henri Mathieu | 24 | France |
| 2006 | French Open | R32 | Aravane Rezaï | 19 | France |
| 2006 | French Open | R32 | Nathalie Dechy | 27 | France |
| 2006 | French Open | R64 | Florent Serra | 25 | France |
| 2006 | French Open | R64 | Mathieu Montcourt | 21 | France |
| 2006 | French Open | R64 | Jérémy Chardy | 19 | France |
| 2006 | French Open | R64 | Sébastien Grosjean | 28 | France |
| 2006 | French Open | R64 | Marc Gicquel | 29 | France |
| 2006 | French Open | R64 | Richard Gasquet | 19 | France |
| 2006 | French Open | R64 | Mathilde Johansson | 21 | France |
| 2006 | French Open | R64 | Marion Bartoli | 21 | France |
| 2006 | French Open | R64 | Émilie Loit | 26 | France |
| 2006 | French Open | R64 | Alizé Cornet | 16 | France |
| 2006 | French Open | R128 | Olivier Patience | 26 | France |
| 2006 | French Open | R128 | Gilles Simon | 21 | France |
| 2006 | French Open | R128 | Jean-Christophe Faurel | 25 | France |
| 2006 | French Open | R128 | Nicolas Mahut | 24 | France |
| 2006 | French Open | R128 | Fabrice Santoro | 33 | France |
| 2006 | French Open | R128 | Thierry Ascione | 25 | France |
| 2006 | French Open | R128 | Michaël Llodra | 26 | France |
| 2006 | French Open | R128 | Tatiana Golovin | 18 | France |
| 2006 | French Open | R128 | Stéphanie Foretz | 25 | France |
| 2006 | French Open | R128 | Séverine Beltrame | 26 | France |
| 2006 | French Open | R128 | Pauline Parmentier | 20 | France |
| 2006 | French Open | R128 | Stéphanie Cohen-Aloro | 23 | France |
| 2006 | French Open | R128 | Youlia Fedossova | 17 | France |
| 2006 | French Open | R128 | Camille Pin | 24 | France |
| 2006 | French Open | R128 | Aurélie Védy | 25 | France |
| 2006 | French Open | R128 | Virginie Pichet | 23 | France |
| 2006 | French Open | R128 | Virginie Razzano | 23 | France |
| 2006 | Australian Open | W | Amélie Mauresmo | 26 | France |
| 2006 | Australian Open | Q | Sébastien Grosjean | 27 | France |
| 2006 | Australian Open | Q | Fabrice Santoro | 33 | France |
| 2006 | Australian Open | R16 | Paul-Henri Mathieu | 24 | France |
| 2006 | Australian Open | R32 | Gilles Simon | 21 | France |
Open Era Grand Slam Tennis