| Year | Tournament | Result | Player | Age | Nation |
|---|---|---|---|---|---|
| 1994 | Wimbledon | R128 | Karine Quentrec | 24 | France |
| 1994 | Wimbledon | R128 | Iva Majoli | 16 | Croatia |
| 1994 | Wimbledon | R128 | Rene Simpson | 28 | Canada |
| 1994 | Wimbledon | R128 | Barbara Schett | 18 | Austria |
| 1994 | Wimbledon | R128 | Petra Schwarz | 22 | Austria |
| 1994 | Wimbledon | R128 | Tami Whitlinger | 25 | United States |
| 1994 | Wimbledon | R128 | Caroline Vis | 24 | Netherlands |
| 1994 | Wimbledon | R128 | Åsa Svensson | 19 | Sweden |
| 1994 | Wimbledon | R128 | Karina Habšudová | 20 | Slovakia |
| 1994 | Wimbledon | R128 | Joanette Kruger | 20 | South Africa |
| 1994 | Wimbledon | R128 | Leila Meshki | 26 | Georgia |
| 1994 | Wimbledon | R128 | Angélica Gavaldón | 20 | Mexico |
| 1994 | Wimbledon | R128 | Ludmila Richterová | 17 | Czech Republic |
| 1994 | Wimbledon | R128 | Katerina Maleeva | 25 | Bulgaria |
| 1994 | French Open | W | Sergi Bruguera | 23 | Spain |
| 1994 | French Open | W | Arantxa Sánchez Vicario | 22 | Spain |
| 1994 | French Open | F | Alberto Berasategui | 20 | Spain |
| 1994 | French Open | F | Mary Pierce | 19 | France |
| 1994 | French Open | S | Jim Courier | 23 | United States |
| 1994 | French Open | S | Magnus Larsson | 24 | Sweden |
| 1994 | French Open | S | Conchita Martínez | 22 | Spain |
| 1994 | French Open | S | Steffi Graf | 24 | Germany |
| 1994 | French Open | Q | Pete Sampras | 22 | United States |
| 1994 | French Open | Q | Hendrik Dreekmann | 19 | Germany |
| 1994 | French Open | Q | Andriy Medvedev | 19 | Ukraine |
| 1994 | French Open | Q | Goran Ivanišević | 22 | Croatia |
| 1994 | French Open | Q | Petra Schwarz | 22 | Austria |
| 1994 | French Open | Q | Sabine Hack | 24 | Germany |
| 1994 | French Open | Q | Inés Gorrochategui | 20 | Argentina |
| 1994 | French Open | Q | Julie Halard-Decugis | 23 | France |
| 1994 | French Open | R16 | Mikael Tillström | 22 | Sweden |
| 1994 | French Open | R16 | Olivier Delaître | 26 | France |
| 1994 | French Open | R16 | Jacco Eltingh | 23 | Netherlands |
| 1994 | French Open | R16 | Andrea Gaudenzi | 20 | Italy |
| 1994 | French Open | R16 | Pat Rafter | 21 | Australia |
| 1994 | French Open | R16 | Jaime Yzaga | 26 | Peru |
| 1994 | French Open | R16 | Javier Frana | 27 | Argentina |
| 1994 | French Open | R16 | Aaron Krickstein | 26 | United States |
| 1994 | French Open | R16 | Anke Huber | 19 | Germany |
| 1994 | French Open | R16 | Alexia Dechaume-Balleret | 24 | France |
| 1994 | French Open | R16 | Irina Spîrlea | 20 | Romania |
| 1994 | French Open | R16 | Shaun Stafford | 25 | United States |
| 1994 | French Open | R16 | Natasha Zvereva | 23 | Belarus |
| 1994 | French Open | R16 | Amanda Coetzer | 22 | South Africa |
| 1994 | French Open | R16 | Iva Majoli | 16 | Croatia |
| 1994 | French Open | R16 | Ruxandra Dragomir | 21 | Romania |
| 1994 | French Open | R32 | Richey Reneberg | 28 | United States |
| 1994 | French Open | R32 | Jonas Björkman | 22 | Sweden |
| 1994 | French Open | R32 | Yevgeny Kafelnikov | 20 | Russia |
| 1994 | French Open | R32 | Arnaud Boetsch | 25 | France |
Open Era Grand Slam Tennis