| Year | Tournament | Result | Player | Age | Nation |
|---|---|---|---|---|---|
| 2002 | Australian Open | R128 | Paul-Henri Mathieu | 20 | France |
| 2002 | Australian Open | R128 | Cyril Saulnier | 26 | France |
| 2002 | Australian Open | R128 | Olivier Patience | 21 | France |
| 2002 | Australian Open | R128 | Mary Pierce | 26? | France |
| 2002 | Australian Open | R128 | Sandrine Testud | 29 | France |
| 2002 | Australian Open | R128 | Virginie Razzano | 18 | France |
| 2002 | Australian Open | R128 | Céline Beigbeder | 26 | France |
| 2002 | Australian Open | R128 | Émilie Loit | 22 | France |
| 2002 | Australian Open | R128 | Marion Bartoli | 17 | France |
| 2001 | US Open | Q | Amélie Mauresmo | 22 | France |
| 2001 | US Open | R16 | Arnaud Clément | 23 | France |
| 2001 | US Open | R16 | Nathalie Tauziat | 33 | France |
| 2001 | US Open | R16 | Sandrine Testud | 29 | France |
| 2001 | US Open | R64 | Fabrice Santoro | 28 | France |
| 2001 | US Open | R64 | Jérôme Golmard | 27 | France |
| 2001 | US Open | R64 | Nicolas Escudé | 25 | France |
| 2001 | US Open | R64 | Nathalie Dechy | 22 | France |
| 2001 | US Open | R64 | Virginie Razzano | 18 | France |
| 2001 | US Open | R64 | Émilie Loit | 22 | France |
| 2001 | US Open | R128 | Cédric Pioline | 32 | France |
| 2001 | US Open | R128 | Julien Boutter | 27 | France |
| 2001 | US Open | R128 | Sébastien de Chaunac | 23 | France |
| 2001 | US Open | R128 | Cyril Saulnier | 26 | France |
| 2001 | US Open | R128 | Arnaud Di Pasquale | 22 | France |
| 2001 | US Open | R128 | Sébastien Grosjean | 23 | France |
| 2001 | US Open | R128 | Antony Dupuis | 28 | France |
| 2001 | US Open | R128 | Anne-Gaëlle Sidot | 22 | France |
| 2001 | US Open | R128 | Alexandra Fusai | 27 | France |
| 2001 | Wimbledon | Q | Nicolas Escudé | 25 | France |
| 2001 | Wimbledon | Q | Nathalie Tauziat | 33 | France |
| 2001 | Wimbledon | R16 | Arnaud Clément | 23 | France |
| 2001 | Wimbledon | R16 | Sandrine Testud | 29 | France |
| 2001 | Wimbledon | R32 | Fabrice Santoro | 28 | France |
| 2001 | Wimbledon | R32 | Sébastien Grosjean | 23 | France |
| 2001 | Wimbledon | R32 | Amélie Mauresmo | 21 | France |
| 2001 | Wimbledon | R64 | Stéphane Huet | 30 | France |
| 2001 | Wimbledon | R64 | Cédric Pioline | 32 | France |
| 2001 | Wimbledon | R64 | Antony Dupuis | 28 | France |
| 2001 | Wimbledon | R64 | Émilie Loit | 22 | France |
| 2001 | Wimbledon | R64 | Nathalie Dechy | 22 | France |
| 2001 | Wimbledon | R128 | Michaël Llodra | 21 | France |
| 2001 | Wimbledon | R128 | Julien Boutter | 27 | France |
| 2001 | Wimbledon | R128 | Sarah Pitkowski-Malcor | 25 | France |
| 2001 | Wimbledon | R128 | Anne-Gaëlle Sidot | 21 | France |
| 2001 | Wimbledon | R128 | Stéphanie Foretz | 20 | France |
| 2001 | Wimbledon | R128 | Virginie Razzano | 18 | France |
| 2001 | French Open | S | Sébastien Grosjean | 23 | France |
| 2001 | French Open | R16 | Fabrice Santoro | 28 | France |
| 2001 | French Open | R16 | Sandrine Testud | 29 | France |
| 2001 | French Open | R32 | Antony Dupuis | 28 | France |
Open Era Grand Slam Tennis